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Universally nondiverging Grüneisen parameter at critical points

According to Boltzmann-Gibbs (BG) statistical mechanics, the thermodynamic response, such as the isothermal susceptibility, at critical points (CPs) presents a divergent-like behavior.

An appropriate parameter to probe both classical and quantum CPs is the so-called Grüneisen ratio Γ. Motivated by the results reported in [Phys. Rev. B 108, L140403 (2023)10.1103/PhysRevB.108.L140403], we extend the quantum version of Γ to the nonadditive q-entropy Sq.

Our findings indicate that using Sq at the unique value of q restoring the extensivity of the entropy, Γ is universally nondiverging at CPs.

We unprecedentedly introduce Γ in terms of Sq, being BG recovered for q→1. We thus solve a long-standing problem related to the illusory diverging susceptibilities at CPs.

S.M. Soares, L. Squillante, H.S. Lima, C. Tsallis, M. de Souza, Universally nondiverging Grüneisen parameter at critical points, Physical Review B 111(6) (2025) l060409.

Henrique Santos Lima

Constantino Tsallis, External Faculty at the Complexity Science Hub, celebrates his 80th birthday

Constantino Tsallis

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